The couple's Jolie-Pitt Foundation just donated $1 million to help displaced people in Pakistan.
António Guterres, the head of the agency thanked the foundation for its donation, calling Pakistan's plight "the most challenging humanitarian crisis of the past decade."
Angie is currently in Washington, D.C., where she will talk about aiding refugees with Secretary of State Hillary Clinton as they celebrate World Refugee Day.
Meanwhile, Pitt has started work in Los Angeles on his latest film, Moneyball , while Jolie just wrapped up her latest film Salt in NY. Angie will now be a stay at home mom while Brad shoots his movie. They've got a interesting arrangement that is definitely working for them.