Dressed down and sporting sunglasses, the actors visited London's National Portrait Gallery where they checked out the Lucian Freud exhibit, which is in its final weeks.
After spending some time viewing the works in the Gallery, the couple made their way to a waiting car - no kids in sight!
Say what you want about these two but they seem to try to do things without much fuss.
A spokesperson for the gallery tells Hollyscoop, "It was an impromptu visit. They made their way to the Lucian Freud exhibit and there was no request for any special arrangements for viewing."
The Lucian Freud exhibit has been a hit for the gallery and celebrities alike since its February 9 opening to the public. Aside from the Jolie-Pitt's, Catherine, the Duchess of Cambridge attended a preview of the paintings on February 8.
The entire Jolie-Pitt family is expected to head to France soon where Brad is premiering his film, "Killing Them Softly" at the Cannes Film Festival.